What does it look like?
What is it?
The pyrochlore crystal structure is a cubic that can be described by the spacegroup Fd-3m. The general formula for these materials are A2B2O6 and A2B2O7 where the A and B species are typically either rare earth ions, or transition metal species. The A and B sites form an array of interlinked tetrahedral, which are 3 sided shapes consisting of triangles and it is this that often leads to exotic magnetic properties.
Dy2Ti2O7 and Ho2Ti2O7 are two such pyrochlore systems which have been called “spin-ice”. This stems from the “2in-2out” magnetic spin structure which can be likened to the water-ice structure where for each oxygen ion, two protons (or hydrogens) must be in the near position and two in the far position. Dy2Ti2O7 and Ho2Ti2O7 are also part of a larger family of geometrically frustrated pyrochlores in which the magnetic “spins” cannot simultaneously satisfy their antiferromagnetic (antiparallel) spin arrangements with all of their neighbouring spins due to the geometric constraints, similar to Jarosite (Fig. 1).Both Dy2Ti2O7 and Ho2Ti2O7 received a lot of attention in the media in 2009 due to the observation of the elusive magnetic monopoles as emergent quasi-particles. We all know that every magnet has a north and south pole and that if we cut these dipole magnets in half, we fail to separate the ends into monopoles, but instead create two new magnets each with a north and south pole. However due to the topology of the spin structure in Dy2Ti2O7 and Ho2Ti2O7, under certain applied field and low temperature sample conditions, magnetic monopoles could be formed within the lattice. The application of a small magnetic field could flip one of the spins such that one tetrahedron was a “3in-1out” (South) pole and its neighbouring tetrahedron was a “1in-3out” (North) pole (See Fig. 1). It was shown that with no additional energy input, these two “monopoles” could move away from each other such that locally there appeared to be an isolated monopole. In actual fact these two monopoles were connected by an extremely long, tensionless Dirac string. However the sensational news of observing a “magnetic monopole” for the first time became a hot topic on news websites around the world – even being mentioned in “The Big Bang Theory”.
Where did the structure come from?
This crystal structure was taken from van de Velde et al., Powder Diffraction 5 (4), pp229-31 (1990) and displays the pyrochlore structure for the related Tb2Ti2O7 material. Each of the A2Ti2O7 materials (A = rare earth) forms a cubic structure with a lattice parameter close to 10 Å.